WebJul 30, 2024 · In this work, the Flory–Rehner equation is revisited to evidence the dependency of the interaction parameter on both polymer volume fraction and … WebIn this paper, we explain the increased swelling of crosslinked polysaccharide microgels by the increase of sugar concentration using a modified Flory–Rehner theory. This theory is validated via the investigation of the swelling of dextran microgels in sugar solutions, which can be viewed as a model system for crosslinked starch in sugar ...
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Web3. The heat of mixing of polymer and solvent, which may be positive, negative, or zero. Usually it is slightly positive, opposing mixing. The FloryRehner equation may be written v2 13 2 - [ln (1 - v2 ) + v2 + c1v2 ] = V1 n v2 - 2 (9.92) where v2 is the volume fraction of polymer in the swollen mass, V1 is the molar volume of the solvent, and c1 ... WebApr 10, 2009 · where ϕ = volume fraction of the polymer in the swollen system, so the volume swelling ratio, S = 1/ϕ; ν = crosslink density (mole/volume); V = molar volume of the solvent, and χ = Flory–Huggins parameter representing the solvent–polymer interaction energy.Typical use of this equation is to measure the crosslink density by measuring the … dan mccafferty albums
Revisiting the Flory–Rehner equation: taking a closer look at the Flory …
WebFlory-Rehner Theory of Polymer Network Swelling The thermodynamics of swelling of network structures was first investigated by Paul Flory and J. Rehner in the early 1940s. … WebCERIでは修正Flory-Rehnerの式を用いた平衡膨潤法、あるいはFloryの理論式を用いた膨潤圧縮法によりゴム試料の架橋密度(網目鎖濃度) 2),3) を測定可能です。2つの手法にはそれぞれ長所・短所がありますので、測 … Webところで架橋ポリマーと溶媒との間には以下のFlory−Rehnerの式(II)が成立つことが知られている(非特許文献1参照)。 一方、ポリマーと溶媒が相溶するためには以下の式(III)の関係を満足することが必要であることも知られている(非特許文献2参照 ... birthday gift ideas for your sister